(Disclaimer: below is just my opinion. Agree or disagree at your leisure)
Sounds like you have buyers remorse. You shouldn't. Challenger R/T w/ 5.7L HEMI is an awesome car as is.
My fist bit of advise is drive it for a while, you might find it has plenty of power. Even if you can make it faster than a Scat Pack there will ALWAYS be faster cars. After you beat a SP you will want to be faster than a HC.
If you didn't have the $$$ to buy a SP (Scat Pack), the harsh reality is, you probably won't have the money to make your car as fast as a SP. The cheapest way to add power is Super Charger (or NOS). If your not racing it's probably not worth the time and money, at a certain power level you need to start beefing up the rear end also, so we're not just talking engine mods. If you're not racing and just doing it for the fun and thrill, that is totally okay in my book.
If you do want to mod, don't let any one dissuade you. Mod away. I think modding is fun, I get swept up in it myself. But unless your a mechanic or can DIY, it's not cheap to mod a MOPAR.
When you do mod, I recommend you do not using the SP as a bench mark. Don't try to match the spec of the 6.4L. Just try to squeeze as much power as your wallet will allow from the 5.7. There are some Damn fast moded RTs out there. My recommendation is SC it if your on a budget. However, I totally get wanting a N/A car. I prefer it myself over FI. (I've owned, and own, SC and TC cars, I much prefer N/A).
Your first mod (IMO) should be better tires (sometimes meaning new wheels also). ALL the HEMI cars suffer from lack of traction at launch. I upgraded wheels and put 315s on the back (I have a SP BTW). Night at day difference. I was running 4.8 second 0-60 with stock wheels. Now I average 4.3sec with a 4.2 my best. Might not seam like much on paper But it's a few car thength @ 60mph. I did have to spend upwards of $3k to do it tough. (New wheels needed for the wider rear tires).
Not the answer you were looking for maybe but some things to think about.
Oh, and all the neighsayers that insist the 6.4L and 5.7L engines don't take bolt-ons well,... Well, they have been proven wrong. The key is needing a tune to use the mods to their full potential.